Engineering nanorafts of calixarene polyphosphonates

Tim Clark; M. Makha; A. Sobolev; H. Rohrs; J. Atwood; C. Raston

doi:10.1002/chem.200701472

Engineering nanorafts of calixarene polyphosphonates

Tim Clark, M. Makha, A. Sobolev, H. Rohrs, J. Atwood, C. Raston

Research output: Contribution to journal › Article › peer-review

Abstract

The water-soluble calix[4]arene bearing p-substituted phosphonic acid groups is accessible in five steps in overall 62 % yield, with the hydrogen-bonding prowess of the acidic groups dominating its self-assembly processes. These include the formation of 3.0(3) nm and 20(2) nm nanorafts of the calixarene in water using spinning disc processing, stabilized by acetonitrile, and nanorafts in the gas phase (

Original language	English
Pages (from-to)	3931-3938
Number of pages	8
Journal	Chemistry
Volume	14
Issue number	13
DOIs	https://doi.org/10.1002/chem.200701472
Publication status	Published - 2008

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title = "Engineering nanorafts of calixarene polyphosphonates",

abstract = "The water-soluble calix[4]arene bearing p-substituted phosphonic acid groups is accessible in five steps in overall 62 % yield, with the hydrogen-bonding prowess of the acidic groups dominating its self-assembly processes. These include the formation of 3.0(3) nm and 20(2) nm nanorafts of the calixarene in water using spinning disc processing, stabilized by acetonitrile, and nanorafts in the gas phase (",

author = "Tim Clark and M. Makha and A. Sobolev and H. Rohrs and J. Atwood and C. Raston",

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AU - Makha, M.

AU - Sobolev, A.

AU - Rohrs, H.

AU - Atwood, J.

AU - Raston, C.

PY - 2008

Y1 - 2008

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DO - 10.1002/chem.200701472

M3 - Article

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VL - 14

SP - 3931

EP - 3938

JO - Chemistry

JF - Chemistry

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Engineering nanorafts of calixarene polyphosphonates

Abstract

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