Investigation of the CaO-Al2O3-SiO2-CaSO4-CaCO3-H2O system at 25 degrees C by thermodynamic calculation

D. Damidot, S. J. Barnett, F. P. Glasser, D. E. Macphee

Research output: Contribution to journalArticlepeer-review

Abstract

The phase diagram of the CaO-Al2O3-SiO2-CaSO4-CaCO3-H2O system relevant to cement has been calculated at 25degreesC and 1 bar pressure. It is composed of 331 stable phase assemblages in equilibrium with the aqueous phase and contains 30 invariant points with 15 solids. Thaumasite appears to be a stable phase with a wide stability domain. Compared to ettringite, thaumasite is stable to lower pH and generally demands higher sulphate concentrations to be stable.
Original languageEnglish
Pages (from-to)69-76
Number of pages8
JournalAdvances in Cement Research
Volume16
Publication statusPublished - 2004

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