Multiply bonded metal(II) acetate (rhodium, ruthenium, and molybdenum) complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand

Nico Fritsch; Christian R. Wick; Thomas  Waldmann; Pavlo Dral; Johannes Tucher; Frank Heinemann; Tatyana E. Shubina; Tim Clark; Nicolai Burzlaff

doi:10.1021/ic501435a

Multiply bonded metal(II) acetate (rhodium, ruthenium, and molybdenum) complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand

Nico Fritsch
, Christian R. Wick
, Thomas Waldmann
, Pavlo Dral
, Johannes Tucher
, Frank Heinemann
, Tatyana E. Shubina
, Tim Clark
, Nicolai Burzlaff

Friedrich-Alexander University Erlangen-Nürnberg

Research output: Contribution to journal › Article › peer-review

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Abstract

The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported. The acetate-bridged paddlewheel metal(II) complexes [M2(O2CCH3)4(trans-bie)]n with M = Rh, Ru, Mo, and Cr are linked by the trans-bie ligand to give a one-dimensional alternating chain. Density functional theory and CASSCF/CASPT2 calculations are used to analyze the metal−metal multiple bonds within the new polymers.

Original language	English
Pages (from-to)	12305-12314
Journal	Inorganic Chemistry
Volume	53
Issue number	23
Early online date	13 Nov 2014
DOIs	https://doi.org/10.1021/ic501435a
Publication status	Published - 2014

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10.1021/ic501435a

NicoAcetate_InorgChem_revised_17092014
This document is the Accepted Manuscript version of a Published Work that appeared in final form in [JournalTitle], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/ic501435a
Accepted author manuscript (Post-print), 3.92 MBLicence: CC BY

http://pubs.acs.org/doi/abs/10.1021/ic501435a

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@article{b291fac521b841b6aa4c4ed2a7353ad4,

title = "Multiply bonded metal(II) acetate (rhodium, ruthenium, and molybdenum) complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand",

abstract = "The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported. The acetate-bridged paddlewheel metal(II) complexes [M2(O2CCH3)4(trans-bie)]n with M = Rh, Ru, Mo, and Cr are linked by the trans-bie ligand to give a one-dimensional alternating chain. Density functional theory and CASSCF/CASPT2 calculations are used to analyze the metal−metal multiple bonds within the new polymers.",

author = "Nico Fritsch and Wick, \{Christian R.\} and Thomas Waldmann and Pavlo Dral and Johannes Tucher and Frank Heinemann and Shubina, \{Tatyana E.\} and Tim Clark and Nicolai Burzlaff",

note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in [JournalTitle], copyright {\textcopyright} American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/ic501435a",

year = "2014",

doi = "10.1021/ic501435a",

language = "English",

volume = "53",

pages = "12305--12314",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "23",

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TY - JOUR

T1 - Multiply bonded metal(II) acetate (rhodium, ruthenium, and molybdenum) complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand

AU - Fritsch, Nico

AU - Wick, Christian R.

AU - Waldmann, Thomas

AU - Dral, Pavlo

AU - Tucher, Johannes

AU - Heinemann, Frank

AU - Shubina, Tatyana E.

AU - Clark, Tim

AU - Burzlaff, Nicolai

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in [JournalTitle], copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/ic501435a

PY - 2014

Y1 - 2014

N2 - The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported. The acetate-bridged paddlewheel metal(II) complexes [M2(O2CCH3)4(trans-bie)]n with M = Rh, Ru, Mo, and Cr are linked by the trans-bie ligand to give a one-dimensional alternating chain. Density functional theory and CASSCF/CASPT2 calculations are used to analyze the metal−metal multiple bonds within the new polymers.

AB - The synthesis and structural characterization of new coordination polymers with the N,N-donor ligand trans-1,2-bis(N-methylimidazol-2-yl)ethylene (trans-bie) are reported. The acetate-bridged paddlewheel metal(II) complexes [M2(O2CCH3)4(trans-bie)]n with M = Rh, Ru, Mo, and Cr are linked by the trans-bie ligand to give a one-dimensional alternating chain. Density functional theory and CASSCF/CASPT2 calculations are used to analyze the metal−metal multiple bonds within the new polymers.

U2 - 10.1021/ic501435a

DO - 10.1021/ic501435a

M3 - Article

SN - 0020-1669

VL - 53

SP - 12305

EP - 12314

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 23

ER -

Multiply bonded metal(II) acetate (rhodium, ruthenium, and molybdenum) complexes with the trans-1,2-Bis(N-methylimidazol-2-yl)ethylene Ligand

Abstract

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