TY - JOUR
T1 - Silver nanoparticulate enhanced aqueous silane/siloxane exterior facade emulsions and their efficacy against algae and cyanobacteria biofouling
AU - MacMullen, James
AU - Zhang, Zhong Yi
AU - Dhakal, Hom
AU - Radulovic, Jovana
AU - Karabela, Alkistis
AU - Tozzi, Gianluca
AU - Hannant, Samuel
AU - Ali Alshehri, Mohammed
AU - Buhe, Vincent
AU - Herodotou, Constandinos
AU - Totomis, Miltiadis
AU - Bennett, Nick
N1 - NOTICE: this is the author’s version of a work that was accepted for publication in 'International biodeteriation and biodegradation'. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Sep 2014, International iodeterioration & biodegradation. 93, p. 54-62 10.1016/j.ibiod.2014.05.009
PY - 2014/9
Y1 - 2014/9
N2 - Silver nanoparticulate enhanced aqueous silane/siloxane emulsions and their efficacy against biofouling mechanisms are presented within this study. Different concentrations of silver nanoparticulates were added into viscous shear-thinning aqueous treatments and key attributes required for facade remedial applications assessed. Water repellence, biofouling resistance, and aesthetical alteration were studied to assess key treatment attributes. In addition, assessment of the porosity, sorptivity, and treatment depth was used to identify penetration and facade protection efficacy and morphological alteration of the masonry substrate. Results showed that silver nanoparticulate incorporation did not impede treatment penetration, better water repellent attributes were achieved with increased concentration while effectively conserving the morphology and aesthetics of the substrate. It was concluded that the reducedbioreceptivity observed primarily stemmed from the silver nanoparticulates ability to sanitise the surface, and that only small concentrations (<0.5%wt) were required to attain significantly beneficial improvements. Treatments were deemed practically and commercially viable for retrofit and heritage projects.
AB - Silver nanoparticulate enhanced aqueous silane/siloxane emulsions and their efficacy against biofouling mechanisms are presented within this study. Different concentrations of silver nanoparticulates were added into viscous shear-thinning aqueous treatments and key attributes required for facade remedial applications assessed. Water repellence, biofouling resistance, and aesthetical alteration were studied to assess key treatment attributes. In addition, assessment of the porosity, sorptivity, and treatment depth was used to identify penetration and facade protection efficacy and morphological alteration of the masonry substrate. Results showed that silver nanoparticulate incorporation did not impede treatment penetration, better water repellent attributes were achieved with increased concentration while effectively conserving the morphology and aesthetics of the substrate. It was concluded that the reducedbioreceptivity observed primarily stemmed from the silver nanoparticulates ability to sanitise the surface, and that only small concentrations (<0.5%wt) were required to attain significantly beneficial improvements. Treatments were deemed practically and commercially viable for retrofit and heritage projects.
KW - Silver nanoparticulate
U2 - 10.1016/j.ibiod.2014.05.009
DO - 10.1016/j.ibiod.2014.05.009
M3 - Article
SN - 0964-8305
VL - 93
SP - 54
EP - 62
JO - International Biodeterioration & Biodegradation
JF - International Biodeterioration & Biodegradation
ER -