In common with most thrust belts, the Moine Thrust Zone, Scotland, preserves a foreland-propagating sequence of thrusting. However, significant examples of local to regional overstep sequences are also recognized and their interpretation remains controversial. Remapping of the northernmost Moine Thrust Zone has defined a thick belt of mylonites in the centre of which lies the ductile WNW-directed Moine Thrust. The base of the mylonite belt, however, is marked by a regionally significant, low-angle, west-directed brittle fault, here termed the Lochan Riabhach Thrust, that truncates thrust-related structures in its footwall. Comparison of the tectonic stratigraphy of the mylonite belt with that preserved in a downfaulted outlier to the west at Durness indicates that the Lochan Riabhach Thrust cuts down-section in its footwall and therefore appears to be extensional. Locally, it is unequivocally breached by underlying imbricate thrusts. We prefer to interpret the Lochan Riabhach ‘Thrust’ as an extensional fault that formed during a hiatus in thrust stacking. We relate this faulting episode to the changes in the stability of the evolving orogenic wedge and reiterate that such extensional faults may be common, although possibly unrecognized, features in many other thrust belts.