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An aluminophosphate molecular sieve with 36 crystallographically distinct tetrahedral sites

Research output: Contribution to journalArticlepeer-review

  • Jun Kyu Lee
  • Alessandro Turrina
  • Liangkui Zhu
  • Seungwan Seo
  • Daliang Zhang
  • Professor Paul Cox
  • Paul A. Wright
  • Shilun Qiu
  • Suk Bong Hong
The structure of the new medium-pore aluminophosphate molecular sieve PST-6 is determined by the combined use of rotation electron diffraction tomography, synchrotron X-ray powder diffraction, and computer modeling. PST-6 was prepared by calcination of another new aluminophosphate material with an unknown structure synthesized using diethylamine as a structure-directing agent, which is thought to contain bridging hydroxy groups. PST-6 has 36 crystallographically distinct tetrahedral sites in the asymmetric unit and is thus crystallographically the most complex zeolitic structure ever solved.
Original languageEnglish
Pages (from-to)7480-7483
Number of pages4
JournalAngewandte Chemie International Edition
Volume53
Issue number29
Early online date26 May 2014
DOIs
Publication statusPublished - 14 Jul 2014

Documents

  • An Aluminophosphate Molecular Sieve

    Rights statement: This is the peer reviewed version of the following article: Lee, J. K., Turrina, A., Zhu, L., Seo, S., Zhang, D., Cox, P. A., Wright, P. A., Qiu, S. and Hong, S. B. (2014), An Aluminophosphate Molecular Sieve with 36 Crystallographically Distinct Tetrahedral Sites. Angew. Chem. Int. Ed., 53: 7480–7483. doi:10.1002/anie.201402495, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/anie.201402495/full. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.

    Accepted author manuscript (Post-print), 540 KB, PDF document

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